Both the XML and SQL files produce errors when uploading.

XML

Failed to import shop_order_status cancelled
Failed to import shop_order_status completed
Failed to import product_type external
Failed to import shop_order_status failed
Failed to import product_type grouped
Failed to import shop_order_status on-hold
Failed to import shop_order_status pending
Failed to import shop_order_status processing
Failed to import shop_order_status refunded
Failed to import product_type simple
Failed to import product_type variable
Failed to import product_tag Louncher
Failed to import topic-tag update
Failed to import product_cat Woocommerce
Failed to import topic-tag mikmag responsive
Failed to import topic-tag themedutch
Failed to import topic-tag wordpress

SQL
Error
SQL query:

— — Dumping data for table `wp_options` — INSERT INTO `wp_options` (`option_id`, `option_name`, `option_value`, `autoload`) VALUES (2956, ‘core_background_image’, ‘http://www.responsive-wp-theme.com/wp-content/uploads/2012/06/back-var-3.jpg’, ‘yes’), (3342, ‘core_breadcrumbs’, ‘1’, ‘yes’), (4231, ‘core_category_background_blog’, ‘http://www.responsive-wp-theme.com/wp-content/uploads/2012/06/back-var-2.jpg’, ‘yes’), (4372, ‘core_category_background_design-furniture’, ‘http://www.responsive-wp-theme.com/wp-content/uploads/2012/06/back-var-1.jpg’, ‘yes’), (4375, ‘core_category_background_fashion’, ‘http://www.responsive-wp-theme.com/wp-content/uploads/2012/06/back-var-6.jpg’, ‘yes’), (4564, ‘core_category_background_holiday’, ‘http://www.responsive-wp-theme.com/wp-content/uploads/2012/06/back-var-7.jpg’, ‘yes’), (4567, ‘core_category_background_hotel’, ”, ‘yes’), (7583, ‘core_category_background_hotel-review’, ‘http://www.responsive-wp-theme.com/wp-content/uploads/2012/07/bg-hotel1%5B…%5D

MySQL said: 

#1062 - Duplicate entry 'core_color_button' for key 2

Help please?